\documentclass[tikz]{standalone} \definecolor{ice2}{RGB}{8,81,156} \definecolor{liq2}{RGB}{66,146,198} \begin{document} \begin{tikzpicture} \draw[->,thick] (-0.5,0) -- (9,0) node[right] {$1/\rho$}; \draw[->,thick] (0,-0.5) -- (0,5.5) node[above] {$p(T,\rho)$}; \begin{scope}[scale=1.8] \fill[liq2, opacity=0.5] (0.604,0.64) -- plot[domain=0.604:2.403, smooth, samples=100] (\x, {7.2/(3*\x-1)-3/(\x^2)}) -- (2.403,0.64) -- cycle; \begin{scope} \clip (0, 0) rectangle (5,3); \draw[thick, domain=0.4:4.5, smooth,samples=100] plot (\x, {9/(3*\x-1)-3/(\x^2)}); \draw[ice2,thick, domain=0.4:4.5, smooth,samples=100] plot (\x, {8/(3*\x-1)-3/(\x^2)}); \draw[thick, domain=0.4:4.5, smooth,samples=100] plot (\x, {7.2/(3*\x-1)-3/(\x^2)}); \end{scope} \node[above] at (4,0.7) {$T>T_c$}; \node[ice2,right] at (4.5,0.5) {$T=T_c$}; \node[above] at (4,0.1) {$T