\documentclass[tikz]{standalone} \begin{document} \begin{tikzpicture} \draw[->,thick] (-0.5,0.5) -- (9,0.5) node[right] {$\rho$}; \draw[->,thick] (0,-4.5) -- (0,1.5) node[above] {$f(T,\rho)$}; \draw[thick, domain=0.6:8.5, smooth] plot (\x, {-2.282*(1.3*(\x-0.6))+0.926*(1.3*(\x-0.6))^2-0.153*(1.3*(\x-0.6))^3+0.0081*(1.3*(\x-0.6))^4}); \draw[dashed,thick] (1.8,-1.84) -- (6.7,-4.12); \node[above] at (8.2,-1.3) {$T